Chemical Formula
A chemical formula of a compound is defined as a symbolic representation or notation of atoms constituting an element. The chemical or molecular formula identifies the number of particular atoms of each element present in a compound.
The molecular formula depends on the combining capacity or valency of the elements. Therefore valency is used to find how the atoms of an element will combine with the atom(s) of another element to form a chemical compound.
Sometimes in chemical formula subscripts are also used to represent the ratio of elements in the ionic or non molecular compounds. In case of ionic compounds, chemical formulas are termed as Empirical Formulas.
Following steps are taken to write chemical formula of any compound:
- Write down the symbol of an element
- Write down the valency of each of the element
- Cross over the valency
For example:
Formula of Hydrogen chloride
Valency 1 1
Formula HCl
The valency of Hydrogen and chlorine is one, therefore molecular formula for hydrochloric acid is written as Hcl
Beside the above steps, following three rules must be followed while writing a chemical formula
Rules for writing Chemical Formula
Rule 1:
The valency or charges present on the ion must balance each other.
For example
1. Formula for water: The valency of hydrogen is 1 and that of oxygen is 2. Therefore 2 H atom is required to balance single oxygen atom. Therefore chemical formula for water is written as H2O
Symbol H O
Valency 1 2
Formula H2O
2. Formula for Magnesium Chloride: As the charges on magnesium and chloride ion is 2+ and 1- respectively. Therefore 2 chloride ions are required to balance single magnesium ion.
Symbol Mg Cl
Charge 2+ 1-
Formula MgCl2
Rule 2:
When a metal and non metal constitute a chemical compound, then the symbol of metal is written before the symbol of non metal.
For example:
1. Formula for Sodium chloride: As sodium is a metal and oxygen is a non metal therefore sodium is written first while oxygen is written after it.
Symbol Na Cl
Charge 1+ 1-
Formula NaCl
Rule 3:
When polyatomic ions form a chemical compound, the number of atoms is written after enclosing the polyatomic ion in brackets.
For example:
1. Formula of calcium hydroxide: The formula of calcium hydroxide is written as Ca(OH)2 .Here, the bracket around OH with a subscript 2 indicates that there are two hydroxyl (OH) groups joined to one calcium atom.
Symbol Ca OH
Charge 2+ 1-
Formula Ca(OH)2
2. Formula of calcium carbonate: In this example, brackets are not required as it contains only one ion.
Symbol Ca CO3
Charge 2+ 2-
Formula CaCO3
Chemical Formula for other Compounds
Other examples:
Formula for Aluminum Chloride:
Symbol Al Cl
Charge 3+ 1-
Formula AlCl3
Formula for Copper Nitrate
Symbol Cu NO3
Charge 2+ 1-
Formula CuNO3
Formula for Aluminum Sulphate
Symbol Al SO4
Charge 3+ 2-
Formula Al2 (SO4)3
Formula for Calcium Oxide: As the valency of calcium and oxygen is same but to simplify the formula we write CaO instead of Ca2O2.
Symbol Ca O
Charge 2+ 2-
Formula CaO
Write the chemical formula of Magnesium carbonate, Phosphorus penta chloride, and Hydrogen sulphate.
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Reference Links:
- http://www.vaxasoftware.com/doc_eduen/qui/valencia.pdf
- http://en.wikipedia.org/wiki/Ionic_compound
- http://www.shiva-group.com/images/rt.jpg
- http://www.vaxasoftware.com/doc_eduen/qui/valencia.pdf
- http://www.youtube.com/watch?v=vscoYh6m46M&feature=player_detailpage
- http://www.youtube.com/watch?v=3K5V3kxxlI8&feature=player_detailpage